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Plastic pollution and the technology to beat it

25 March 2019
Using chemistry to solve the problem of plastic recycling

As environmental emergencies go, the explosion of plastic waste is right up there. Professor Thomas Maschmeyer wanted to make plastic valuable enough for people to collect it. What he created might just clean up the planet.

Thomas Maschmeyer

Finding new insights into how the world works has always excited Professor Thomas Maschmeyer, 鈥淚 ask myself: what are fundamental scientific issues preventing us from solving these problems?鈥

Perhaps the only time Professor Thomas Maschmeyer (BSc(Hons) 鈥91 PhD 鈥95) doesn鈥檛 have his head full of research questions is when he鈥檚 mountain biking. 鈥淭rying not to come off a mountain bike as you scream down a hill is a pretty good way to keep your mind away from work,鈥 he says.

Maschmeyer鈥檚 work is both fascinating and important. One aspect is based on a distressing premise: there are beaches in the world where no human has ever set foot that are covered in our garbage.

Most of it is plastic that spews from the rivers where it鈥檚 been dumped, often on an industrial scale. If you think things are bad now, it鈥檚 estimated that by 2050, there will be more weight of plastic in the oceans than fish.

But this article isn鈥檛 about the problem of plastic waste. It鈥檚 about a potential technological solution, which is already leading to the construction of a new kind of plastic recycling plant in the UK.

The technology is based on what鈥檚 called a catalytic hydrothermal reactor (Cat鈥怘TR), an idea originated by Maschmeyer and developed through his start鈥恥p company, Licella. The process was and continues to be strongly supported by the University of Sydney and a highly skilled team of academics, scientists, engineers and entrepreneurs.

鈥淧eople are excited by work that could make a real difference,鈥 says Maschmeyer. 鈥淲ith my students, sometimes we have to tell them to go home because they鈥檙e working too much.鈥

What makes the Cat鈥怘TR process exciting isn鈥檛 that it can recycle plastic. It鈥檚 that it can recycle mixed plastics, often referred to as contaminated, end鈥恛f鈥恖ife plastics. This is the material the Chinese recycling industry no longer accepts from the rest of the world because it is so hard to deal with.

To understand why mixed plastics are difficult to recycle, it helps to understand some basics about plastic itself.

Plastic bottles

The starting point for most plastic is crude oil, which is rich in carbon atoms linked as rings and chains. Each of the carbon atoms is connected to one or more hydrogen atoms. Collectively, these molecules are called hydrocarbons.

When the bonds between the carbon atoms or between the carbon and hydrogen atoms are broken, radicals are generated. By their nature, these radicals are exceptionally eager to bond with other molecules.

On the plus side, inventing new ways for these hydrocarbons to break and recombine has led to the dizzying array of fuels, chemicals and materials that underpin much of modern life, including a huge range of plastics with qualities like transparency, opaqueness, rigidity, squeezability, toughness, delicacy and all the other features that make plastic so endlessly useful.

Imagine if all our containers were still made of glass, pottery or metal. And how would electricity work if there were no non鈥恈onductive plastics?

Now the downside. In conventional, ie, mechanical recycling, plastics can only be processed with other waste made of the same or very well鈥恉efined mixtures of plastic. Using unsorted, random compositions of plastics gives unpredictable results, producing materials of no use to anyone.

That鈥檚 why plastics are sorted strictly into their six classes for recycling, and why most contaminated, end鈥恛f鈥恖ife plastic, which makes up about 50 percent of the world鈥檚 waste plastic, is burned, sent to landfill or indeed dumped into rivers. Things would be so much easier if all types of plastic could be recycled together using a chemical route.

The questions has always been: how? For Maschmeyer, the answer is water.

The Cat-HTR plant

For more than 10 years, this has been the world鈥檚 only large scale Cat-HTR plant. Located on the New South Wales Central Coast, what was learned here will underpin future international plants.

As Cat鈥怘TR Technology breaks plastics down into smaller hydrocarbon components, the system uses water and a mix of catalysts to prevent the intermediate radicals from reacting with each other. The resulting liquid is a stew of stable, distillable molecules that can be easily separated into high value components, ready for reuse.

Of all the current recycling methods, this ease of distillation 鈥 enabled by Cat鈥怘TR鈥檚 stable product mix 鈥 makes the process uniquely efficient.

Maschmeyer鈥檚 method also transforms waste plastic in another hugely significant way.

By converting it into saleable products like waxes, lubrication oils, fuels and gases, which can be used to make new plastics, the waste plastic itself is given monetary value. As Maschmeyer says, 鈥淥nce you give something value, people look after it. They don鈥檛 toss it into rivers; they鈥檒l try and do something with it.鈥

Considering the sheer volume of waste plastic choking the world that can now be monetised, it鈥檚 not surprising Maschmeyer鈥檚 work has attracted commercial interest. The plant in the UK is being built through an infrastructure investor, Armstrong Energy, and when it comes online, it will convert 20,000 tonnes of waste plastic annually.

And that鈥檚 only the beginning. Oil multinationals have expressed strong interest in the oil products the process can produce, and partnerships are being negotiated for more and bigger plants to open around the world, with the Finnish multinational and renewables leader, NESTE Oil, being the first official partner.

It鈥檚 an amazing place to be for Maschmeyer, especially considering where he started.

Thomas Maschmeyer

鈥淧eople realise plastics are entering the food chain and we have a substantial problem,鈥 says Maschmeyer.

Growing up in what was then the rough side of post鈥怱econd World War Hamburg, Maschmeyer was the only youngster in his street to finish 鈥楪ymnasium鈥, Germany鈥檚 senior鈥恡ier of schooling, topping most years. Following his Australian wife to Sydney, he started a double degree at the University of Sydney in science and engineering, later focusing entirely on science.

After his PhD, Maschmeyer worked in London, then Cambridge. He progressed quickly, which he credits to his Lutheran world view and protestant work ethic. By the age of 31 he was in the Netherlands and Head of the Department of Applied Organic Chemistry and Catalysis at the Delft Institute of Chemical Technology. He became Vice Chair of the whole institute a couple of years later.

Missing the hands鈥恛n research he had enjoyed before his appointment to these senior roles, he decided to return to Sydney as a Federation Fellow.

鈥淎lso the kids started to support Dutch soccer teams. I had to put a stop to that,鈥 he says laughing.

He hasn鈥檛 fully avoided senior university postings (until recently he was the Founding Director of the University of Sydney鈥檚 Nano Institute), but he now happily runs a research team, doing work that just earned him the 鈥淎ustralian Science Oscar鈥 鈥 the 2018 Eureka Prize.

鈥淚 have around 15 students doing work in all sorts of areas,鈥 he says. 鈥淚 think I鈥檓 quite good at spotting talent and getting people hooked on a particular journey. And of course, if they鈥檙e successful, I鈥檓 successful. So, it鈥檚 enlightened self鈥恑nterest, really.鈥

With the Cat鈥怘TR initiative well underway, Maschmeyer is pursuing numerous other high鈥恑mpact projects. His current research focus is on another revolutionary technology 鈥 a new generation of batteries for storing renewable energy. But that鈥檚 a whole other story.

Discover more research

Professor Thomas Maschmeyer's research into chemical recycling is only one element of his work. Find out more about his research into nanoscale battery technology听.


Written by George Dodd
Photography by Louise Cooper

Facts & figures

Plastic by the numbers

  • 450 years is the length of time a plastic bottle takes to break down. Nearly every piece of plastic ever made still exists today.
  • 8 million tonnes of plastic waste flow into the oceans every year.
  • 50% of the world's plastic is end-of-life plastic, meaning it isn't able to be recycled.